THE POLYMER SOCIETY OF KOREA

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세션명 고분자구조 및 물성
발표장 제4회장 (203-204)
논문코드 1L4-1
발표일 2018-10-11
발표시간 13:30-14:00
논문제목 Directed Self-Assembly of High-Molecular-Weight Block Copolymer and its Applicability
발표자 류두열
발표자 소속 연세대학교
저자 류두열, 김영식, 이우섭, 조성준
소속 연세대학교
논문초록 Directed self-assembly (DSA) using high-molecular-weight (HMW) block copolymer (BCP) has been a challenging issue because of the difficulty in polymer synthesis and restricted chain mobility. To overcome such barriers, we successfully synthesized HMW BCPs by living anionic polymerization and fabricated nanostructures with period of 100 – 200 nm by solvent vapor annealing (SVA). The resulting morphologies show diversity from 2-dimensional lamellae and hexagonally-packed cylinders to 3-dimensional gyroid network structures and the orientation was controlled by graphoepitaxy and surface modification techniques. Finally, the long-range ordered patterns showed diverse applicabilities to photolithography, enhanced ultrafiltration membrane, pattern transfer and next-generation optical metamaterials, etc..